Quantitative thermal runaway analysis

Discretised Autoclave Thermal Runaway Calorimetry (DATRC) enables understanding of thermal runaway events in unprecedented detail.

Measured Properties

In a single measurement, the following properties are determined:

Vent Gas Release

  • Total gas volume produced

  • Gas generation rate

  • Gas temperature

Energy Release

  • Total energy released in the thermal event

  • Energy fraction remaining in the cell

  • Energy contained in the ejected gas and particles

Particles & Ejecta

  • Total mass of ejected solids

  • Total energy contained in particles

  • Total energy contained in gas

Benefits & Use Cases

Benefits & Test Results

  • Quantify and understand your real thermal runaway risk

  • Identify the true worst-case conditions for later testing (e.g. energy remaining in the cell as a function of SOC)

  • Generate precise inputs for designs and simulations

Cell Development & Selection

  • Compare cell safety using quantitative data

  • Understand the safety impacts of chemistry and mechanical design changes

  • Identify cell bach-to-batch safety variations

Simulation & Data-Driven Engineering

  • Determine propagation risk and accurately size thermal management and protection systems

  • Design vent gas channels based on real-world data

  • Simulate pack behaviour early on, reducing the number of downstream tests

Example Data

Data from three 2170 cell types (4.9 Ah each), triggered by overheating.

Significant differences in the amount of energy remaining in the cell after thermal runaway are observed. Similarly, the amount of released gas, as well as the release rates vary significantly. It can be seen that similar cells can have vastly different safety properties.

Test Details

Limits

  • Cells up to 100 Ah

  • All chemistries, including NMC, LFP, Na-ion, etc.

  • All formats (cylindrical, single-layer and multi-layer pouch, prismatic)

Triggers

  • Nail / needle penetration

  • Local hotspot or full-cell overheating

  • Electrical abuse (short circuit, overcharging, forced discharge, etc.)

Environments

  • Air or reduced oxygen

  • Inert atmosphere (argon, nitrogen)

  • Temperature preconditioning